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http://hdl.handle.net/10267/33454
Title: | Hydrogen Production Catalyzed by a Cobalt Schiff Base Complex |
Authors: | Hutchison, Phillips S. Kiker, Meghan T. Tinker, Cameron W. |
Advisors: | Eckenhoff, William T. (Will) |
Keywords: | Class of 2019;URCAS;Student research;2018 Spring;Chemistry, Department of |
Issue Date: | 27-Apr-2018 |
Abstract: | As the world's population increases, developing new energy sources, such as artificial photosynthetic hydrogen production, is becoming a priority. Recent studies have shown the effectiveness of cobalt complexes with polypyridine ligands acting as catalysts for light driven hydrogen production. 1,1-(pyridine-2,6-diyl)bis(2-(2-pyridinyl)ethyl)ethanimine is a promising ligand because of its electronic similarity to ligands previously used for cobalt catalyzed hydrogen production. Ligands were synthesized following procedures in available literature and subsequently complexed to cobalt using a Co(BF4)3 salt. Recent work has focused on further purification of the ligand to eliminate impurities in the complex. Electrochemical analysis shows redox waves at -0.725V and -2.147V vs Fc/Fc+. In the presence of acetic acid, a catalytic wave, indicative of hydrogen formation, was observed at -2.147 V vs Fc/Fc+. These results suggest that this complex might be suitable in light driven artificial photosiynthetic systems. |
Description: | Presentation by Phillips Hutchison ('19), Meghan Kiker ('19), and Cameron Tinker ('19) delivered at the Rhodes College Undergraduate Research and Creative Activity Symposium (URCAS). |
URI: | http://hdl.handle.net/10267/33454 |
Appears in Collections: | Undergraduate Research and Creative Activity Symposium |
Files in This Item:
File | Description | Size | Format | |
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201804_Hutchison_Kiker_Tinker_HydrogenProd_poster.pdf | 1.16 MB | Adobe PDF | View/Open |
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